A definite +1 for this feature. I completely understand the workaround, but it really isn't viable if you're doing it multiple times a day. Until today, my boss still sends me emails to my personal address.. how did it happen? I happened to send her an Evernote Note. She replied to that email, which placed my personal email in her outlook cache, and for some reason, every time she now composes a new email to me, my personal email pops up before my work email. Moral of the story, it would be a very useful feature to allow multiple address as a FROM when email from Evernote.